How about the WNBC calls. There is no radio station using them, only TV. But if you do a call search on the FCC web site it says there not available.
And that's correct. Because channel 4 in New York is "WNBC," the callsign "WNBC" is not available to any radio station without the permission of NBC. If an FM station could get that permission, it would have to be WNBC-FM. If an AM station could get that permission, it would have to come along with a call change on channel 4 from "WNBC" back to "WNBC-TV," to make "WNBC" available for the AM station.
In practice, NBC is unlikely to grant that permission.